Chemistry – An Asian Journal: Early View
https://onlinelibrary.wiley.com/toc/1861471x/0/030.12.2021 · Stereoselective synthesis of 2,3-dideoxy-β-O-glycosides has been reported herein.C3-(o-cyanobenzoate) ester protected glucal substrates have been efficiently glycosylated under Pd(0) catalyzed Ferrier rearrangement.The reaction was compatible with a large range of alcohol nucleophiles which afforded the rearranged products in high to excellent β-selectivities.